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Nano Physics

Nanomaterials

Introduction

Nanotechnology is a rapidly growing field that involves the study and manipulation of materials at the nanoscale, which is incredibly small - one nanometer is one billionth of a meter. While technology is complex, its potential applications are vast and varied, and many have the potential to benefit people from all walks of life.       

Applications

Nanotechnology has the potential to revolutionize healthcare by improving drug delivery, developing more sensitive diagnostic tools, and creating innovative new medical devices. For example, nanotechnology-based sensors could be used to monitor glucose levels in diabetic patients, or to detect cancer cells in the bloodstream.  It could help us create more efficient and sustainable energy sources by improving solar cells and developing new materials for energy storage. Nanomaterials could also be used to create more efficient lighting systems, reducing energy consumption.  Nanotechnology-based water filters could help remove pollutants and contaminants from drinking water, making it safer and more accessible.

            Nanomaterials have the potential to create stronger and lighter materials for use in construction, transportation, and consumer products. This could lead to more durable and efficient products that are easier to transport and use.  Nanotechnology could help to create smaller and more efficient electronic devices, such as smartphones and laptops. Nanomaterials could also be used to develop flexible and wearable electronics, making them more comfortable and convenient to use.

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History of Nanotechnology

            Nanotechnology is a relatively new field that emerged in the 1980s and 1990s. However, the idea of manipulating matter at the atomic or molecular scale has been around for centuries.  In 1959, physicist Richard Feynman gave a talk titled "There's Plenty of Room at the Bottom" in which he proposed the idea of manipulating and building materials atom by atom. This is considered one of the first discussions of nanotechnology.  In his talk, Feynman discussed the possibility of manipulating and building materials atom by atom.

            Feynman proposed the idea that scientists could use tiny machines to construct and manipulate individual atoms and molecules, thereby enabling the creation of new materials and structures with unprecedented precision. He also discussed the idea of using nanomachines for a variety of practical applications, including computing, medicine, and energy production.  His talk was a visionary glimpse into the potential of nanotechnology, and it inspired many researchers to pursue the field. His ideas were eventually realized, with the development of new tools and techniques that allowed scientists to manipulate materials at the nanoscale. Today, nanotechnology is a thriving field with a wide range of applications in areas such as electronics, medicine, and energy. 

             In the 1980s, researchers began to develop techniques for imaging and manipulating individual atoms and molecules. The invention of the scanning tunneling microscope in 1981 by Gerd Binnig and Heinrich Rohrer allowed scientists to see individual atoms and manipulate them.

            The term "nanotechnology" was coined in 1986 by physicist K. Eric Drexler, who wrote a book called "Engines of Creation: The Coming Era of Nanotechnology." Drexler envisioned a future where nanomachines could build materials and structures atom by atom.  In the 1990s, researchers began to make significant progress in nanotechnology. They developed new tools and techniques for manipulating materials at the nanoscale, including the use of nanotubes and quantum dots.  In 2000, the U.S. government launched the National Nanotechnology Initiative (NNI), a program designed to accelerate the development of nanotechnology.

 

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Nanotechnology Today

In Recent years, Nanotechnology is a rapidly advancing field with a wide range of applications across many different industries. Some of the most exciting developments in nanotechnology include:

            Nanotechnology is being used to develop new drug delivery systems, diagnostic tools, and medical devices. Nanoparticles can be designed to target specific cells or tissues, which could make treatments more effective and reduce side effects. As well it is being used to improve energy efficiency and develop new sources of renewable energy. For example, nanomaterials are being used to develop more efficient solar cells and better batteries.  To develop smaller and faster electronics, Nanoscale materials can be used to make transistors and other components that are smaller and more efficient than traditional materials.  In Environmental remediation, for achieving cleaner energy, nanomaterials are used to remove heavy metals and other pollutants from water.  Thus, new technologies have been developed for cleaning up pollution and reducing waste.

              Nanotechnology has the potential to revolutionize many different industries and improve our lives in countless ways. Moreover, it is being used to develop new materials with unique properties. For instance, nanomaterials can be used to create stronger and more durable materials, as well as materials that are more lightweight and flexible.  As researchers continue to make new breakthroughs in this field, we can expect to see even more exciting developments in the years to come.

Nanostructures

Nanostructures are materials or objects with dimensions at the nanoscale, typically ranging from 1 to 100 nanometers. At this scale, the properties of materials can be significantly different from their bulk counterparts due to quantum mechanical effects and surface area effects.  There are several types of nanostructures such as Nanoparticles, Nanowires, Nanotubes and Nanopores. 

Dimension of Nanomaterials

Size and dimensions of nanomaterials play a crucial role in determining their properties and potential applications.  Many research works are continuously going on to explore new ways to manipulate and control the size and dimensions of nanomaterials. Nanoparticles have a large surface area-to-volume ratio, which can make them more reactive than larger particles. The unique properties of nanomaterials are due to their small size, which can lead to changes in their optical, electrical, mechanical, and chemical properties. The nanomaterials can be classified into three categories based on their dimensions:

  • Zero-dimensional (0D) nanomaterials

  • One-dimensional (1D) nanomaterials

  • Two-dimensional (2D) nanomaterials

0D Nanomaterials

These are nanomaterials with all dimensions in the range of 1-100 nanometers. Examples: nanoparticles, quantum dots, and fullerenes.  Nanoparticles can be made from a variety of materials, such as metals, semiconductors, or polymers and their unique optical, electronic, and magnetic properties make them useful for many applications.

E.g., cadmium selenide (CdSe), cadmium telluride (CdTe), indium phosphide (InP), or zinc selenide (ZnSe), Au, Ag, and Cu metal nanoparticles.

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1D Nanomaterials

These are nanomaterials with two dimensions in the range of 1-100 nanometers and one dimension that is much longer. Examples: nanowires and nanotubes. Nanowires are structures with a diameter of a few nanometers and a length of several micrometers. They are typically made from semiconducting materials and can be used in electronic devices. Nanotubes are hollow tubes with a diameter of a few nanometers and a length of several micrometers. They can be made from a variety of materials, including carbon, metal oxides, and semiconductors. Nanowires and nanotubes have high aspect ratios, which can make them more flexible and stronger than bulk materials. Nanotubes have unique mechanical, electrical, and thermal properties that make them useful for many applications.

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Two-Dimensional (2D) Nanomaterials

These are nanomaterials with one dimension in the range of 1-100 nm and two dimensions that are much longer. Examples of two-dimensional nanomaterials include graphene and other 2D materials. 2D materials have unique electronic properties due to their atomic thickness. E.g., metal nanosheets, graphene-based materials, transition metal oxides/dichalcogenides.

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Different Types of Nanoparticles

Nanoparticles are tiny particles with sizes between 1 and 100 nanometers. There are various types of nanoparticles, including:

  • Metal nanoparticles

  • Semiconductor nanoparticles

  • Magnetic nanoparticles

  • Carbon nanoparticles

  • Polymeric nanoparticles

  • Lipid nanoparticles

  • Ceramic nanoparticles

Each type has unique properties that make them useful in various fields of science and technology.

Metal Nanoparticles: These are nanoparticles made from metals such as gold, silver, platinum, and copper. Metal nanoparticles have unique physical and chemical properties that make them useful in a wide range of applications such as medical diagnostics, drug delivery, and catalysis.

Semiconductor nanoparticles: e.g., cadmium selenide, zinc oxide, and silicon. used in electronics, solar cells, and biological imaging.

Magnetic Nanoparticles:

  • Made from magnetic materials such as iron oxide and cobalt,

  • used in biomedical applications such as drug delivery and magnetic resonance imaging (MRI)

Carbon Nanoparticles:

  • e.g., carbon nanotubes and graphene,

  • used in electronics, energy storage, and water purification.

Polymeric Nanoparticles:

  • e.g., synthetic or natural polymers such as polystyrene, polyethylene glycol, and chitosan,

  • used in drug delivery and gene therapy.

Lipid nanoparticles: phospholipids and cholesterol

Ceramic Nanoparticles:

  • Ceramic materials such as alumina, silica, and titania

  • used in catalysis, electronic materials, and biomedical applications.

Metal Nanoparticles Overview

            Metal nanoparticles (MNPs) are tiny particles made from metal atoms with dimensions in the range of 1 to 100 nanometers. These particles have unique physical, chemical, and electronic properties that differ from those of the bulk metal material. The surface area-to-volume ratio of metal nanoparticles is very high, which makes them highly reactive and can enhance their properties in certain applications such as electronics, catalysis, biomedical engineering, and materials science.

            MNPs can be made from a variety of metals, including gold, silver, platinum, copper, iron, and more. In recent years, the use of metal nanoparticles in medicine has received significant attention due to their unique properties, such as high biocompatibility, tunable surface chemistry, which make them useful for drug delivery, medical imaging, and cancer therapy.

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